Hair cosmetic composition

ABSTRACT

A hair cosmetic composition, containing the following Components (A) to (E):
         (A) benzyl alcohol, from 0.1 to 2% by mass;   (B) dipropylene glycol, from 0.5 to 20% by mass;   (C) malic acid or a salt thereof, from 0.2 to 10% by mass, in terms of the malic acid; and   (D) lactic acid or a salt thereof, from 0.2 to 10% by mass, in terms of the lactic acid; and   (E) a nonionic surfactant at 2% by mass or less,   wherein a Component (E)/Component (A) mass ratio is from 0 to 5, and   wherein a Component (B)/Component (A) mass ratio is from 1 to 50.

CROSS-REFERENCES TO RELATED APPLICATIONS

The present application is a continuation of U.S. Ser. No. 12/744,933,filed May 27, 2010, which is a National Stage (371) of PCT/JP08/03476,filed Nov. 26, 2008, and claims priority to JP 2007-306397, filed Nov.27, 2007.

FIELD OF THE INVENTION

The present invention relates to hair cosmetic compositions.

BACKGROUND OF THE INVENTION

In recent years, it has been said that owing to the influence ofchemical treatment caused by, for example, hair coloring or physicaltreatment caused by blowing, cuticles on the hair surface peel off orthe hair becomes porous by the efflux of lipids from the inside of thehair and as a result, the hair becomes excessively dry, resistant tofinger combing, unmanageable and lusterless.

Leave-on hair cosmetic compositions mainly used now include emulsiontype products such as hair cream containing wax, higher alcohol andsurfactant to provide the hair with manageability and protect the hairfrom excessive dryness; and gel type products containing a film formingpolymer (set polymer). Such hair cosmetic compositions can temporarilysolve the problems such as poor manageability and excessive dryness bycausing an oil or fat or polymer to adhere to the hair surface, butcannot fundamentally improve the hair luster or manageability.

Some hair cosmetic compositions for improving the hair quality are knownand compositions using a specific organic acid and organic solvent, onwhich an attempt was made to improve the hair quality by acting on theinside of the hair, are known. Of these, leave-on hair cosmeticcompositions containing both malic acid and lactic acid as the organicacid and further containing an organic solvent are proposed (refer toPatent Document 1). Continuous use of this hair cosmetic composition cangradually improve the hair luster and especially improve the setretention property under high humidity, manageability, and hair feel.Such a hair cosmetic composition is disclosed also in Patent Documents 2and 3.

The hair cosmetic composition disclosed in Patent Document 1 has goodaffinity to either wet hair or dry hair when the composition is appliedthereto, but it does not enable sufficient smooth finger combing. Inaddition, even after continuous use, it does not have a sufficienteffect of improving manageability, particularly under high humidity. Thehair cosmetic composition disclosed in Patent Document 2 or 3, on theother hand, does not have a satisfactory effect on affinity and fingercombability when applied to dry hair or wet hair (especially, dry hair).In addition, continuous use thereof does not have a satisfactory effectof improving manageability/finger combability or improving manageabilityunder high humidity.

-   [Patent Document 1] JP-A-2004-189727-   [Patent Document 2] JP-A-2007-186474 (Example 10)-   [Patent Document 3] JP-A-2006-290796 (Example 6 and Example 8)

SUMMARY OF THE INVENTION

The present invention provides a hair cosmetic composition, whichcontains the following Components (A) to (D):

(A) benzyl alcohol, from 0.1 to 2% by mass;

(B) dipropylene glycol, from 0.5 to 20% by mass;

(C) malic acid or a salt thereof, from 0.2 to 10% by mass, in terms ofthe malic acid; and

(D) lactic acid or a salt thereof, from 0.2 to 10% by mass, in terms ofthe lactic acid; and optionally contain a surfactant (E) at aconcentration of 2% by mass or less and at the same, at a Component(E)/Component (A) mass ratio falling within a range of from 0 to 5.

The present invention also provides a hair-quality improving methodincluding applying the hair cosmetic composition to the hair and leavingthe resulting hair without rinsing.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to a hair cosmetic composition capable ofproviding the hair with good affinity, smooth finger combability, andgood hair feel; bringing about an effect of improving the manageabilityof the hair either before rinsing or after rinsing when it iscontinuously applied about three times; and preventing theunmanageability of the hair under high humidity.

The present inventors have found that a hair cosmetic compositioncapable of satisfying the above-described requirement can be obtained byusing two specific organic solvents and two specific organic carboxylicacids in combination and limiting the content of a surfactant to apredetermined level or less.

The content of benzyl alcohol as Component (A) should be from 0.1 to 2%by mass, preferably from 0.12 to 1.5% by mass, more preferably from 0.15to 1.2% by mass from the standpoint of its ability of improving affinityto the hair, improving softness of the hair at the time of applicationand further, improving the manageability of the hair.

The content of dipropylene glycol as Component (B) in the hair cosmeticcomposition of the present invention should be from 0.5 to 20% by mass,preferably from 1 to 15% by mass, more preferably from 1.5 to 10% bymass from the standpoint of its ability of contributing to thesolubilization or stable dispersion of Component (A) and synergisticallyacting with Component (A) to promote an effect of improving luster ormanageability of the hair.

A Component (B)/Component (A) mass ratio is preferably from 1 to 50,more preferably from 3 to 45, even more preferably from 5 to 40 from thestandpoint that Component (A) and Component (B) synergistically act topromote an improvement in the luster or manageability of the hair, andimpart the hair with good affinity and softness.

The content of malic acid or a salt thereof, as Component (C) in thehair cosmetic composition of the present invention should be from 0.2 to10% by mass, preferably from 0.25 to 8% by mass, even more preferablyfrom 0.3 to 6% by mass in terms of malic acid, from the standpoint ofsatisfying both smooth finger combability to wet hair and smooth fingercombability to dry hair and imparting a manageability improving effect.

The content of lactic acid or a salt thereof, as Component (D) in thehair cosmetic composition of the present invention should be from 0.2 to10% by mass, preferably from 0.25 to 8% by mass, more preferably from0.3 to 6% by mass in terms of lactic acid, from the standpoint ofimparting the hair with flexibility, luster and good affinity.

The total content of Component (C) and Component (D) in the haircosmetic composition of the present invention is preferably from 0.4 to15% by mass, more preferably from 0.5 to 14% by mass, even morepreferably from 0.6 to 12% by mass in terms of an acid converted fromthe total amount of the acids and salts thereof, from the standpoint ofimparting good finger combability and smoothness to the hair withoutcausing stickiness or stiffness.

A surfactant as Component (E) may be added to the hair cosmeticcomposition of the present invention at a concentration of 2% by mass orless and at the same time at a Component (E)/Component (A) mass ratiofalling within a range of from 0 to 5. The content of the surfactant, ifit is added, is preferably from 0.02 to 2% by mass, more preferably from0.05 to 1.5% by mass from the standpoint of promoting penetration ofComponent (A) into the hair and promoting an effect of improvingmanageability. From the same standpoint, the Component (E)/Component (A)mass ratio is preferably from 0 to 5, more preferably from 0.5 to 4.5,even more preferably from 1 to 4. As the surfactant, any of cationicsurfactants, nonionic surfactants, amphoteric surfactants, and anionicsurfactants is usable, of which cationic surfactants are preferred.

For example, the following cationic surfactants (i) to (vi) are suitedfor use. Of these, the cationic surfactants (i), (iii), and (v) arepreferred.

(i) Alkyltrimethylammonium Salts

Examples include those represented by the following formula:

R¹—N⁺(CH₃)₃X⁻

[wherein R¹ represents an alkyl group having from 12 to 22 carbon atoms,and X⁻ represents a halide ion (preferably, chloride ion or bromideion)].

Specific examples include cetyltrimethylammonium chloride,stearyltrimethylammonium chloride and behenyltrimethylammonium chloride.

(ii) Alkoxyalkyltrimethylammonium Salts

Examples include those represented by the following formula:

R¹—O—R²—N⁺(CH₃)₃X⁻

[wherein, R² represents an ethylene or trimethylene group, and R¹ and X⁻have the same meanings as described above].(iii) Dialkyldimethylammonium Salts

Examples include those represented by the following formula:

R³ ₂N⁺(CH₃)₂ X⁻

[wherein, R³ represents an alkyl group having from 12 to 22 carbon atomsor a benzyl group and X⁻ has the same meaning as described above].

Specific examples include dialkyldimethylammonium chloride.

(iv) Alkyldimethylamines and Salts Thereof

Examples include those represented by the following formula:

R¹—N(CH₃)₂

[wherein, R¹ has the same meaning as described above].

(v) Alkoxyalkyldimethylamines and Salts Thereof

Examples include those represented by the following formula:

R¹—O—R²—N(CH₃)₂

[wherein, R¹ and R² have the same meanings as described above].

Specific examples include N,N-dimethyl-3-octadecyloxypropylamine andN,N-dimethyl-3-hexadecyloxypropylamine.

(vi) Alkylamidoalkyldimethylamines and Salts Thereof

Examples include those represented by the following formula:

R⁴—C(═O)NH—R²—N(CH₃)₂

[wherein, R⁴ represents an alkyl group having from 11 to 21 carbon atomsand R² has the same meaning as described above].

Examples of the anionic surfactant include alkylbenzene sulfonates,alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, olefinsulfonates, alkane sulfonates, saturated or unsaturated fatty acidsalts, alkyl or alkenyl ether carboxylates, α-sulfofatty acid salts,N-acylamino acid surfactants, mono- or di-phosphate surfactants andsulfosuccinate salts.

Examples of the counterion to the anionic residue of the above-describedanionic surfactants include alkali metal ions such as sodium ion andpotassium ion, alkaline earth metal ions such as calcium ion andmagnesium ion, ammonium ions, and alkanolamines having from 1 to 3alkanol groups with 2 or 3 carbon atoms (such as monoethanolamine,diethanolamine, triethanolamine and triisopropanolamine).

Examples of the nonionic surfactant include polyoxyalkylene alkylethers, polyoxyalkylene alkenyl ethers, higher fatty acid sucroseesters, polyglycerin fatty acid esters, higher fatty acid mono- ordiethanolamides, polyoxyethylene hydrogenated castor oils,polyoxyethylene sorbitan fatty acid esters, polyoxyethylene sorbitolfatty acid esters, alkyl saccharide surfactants, alkylamine oxides, andalkyl amidoamine oxides. Of these, polyoxyalkylene alkyl ethers andpolyoxyethylene hydrogenated castor oils are preferred, withpolyoxyethylene alkyl ethers being more preferred.

As the amphoteric surfactant, imidazolines, carbobetaines,amidobetaines, sulfobetaines, hydroxysulfobetaines, andamidosulfobetaines may be used.

In the hair cosmetic composition of the present invention,2-benzyloxyethanol may be incorporated as Component (F) at aconcentration of 0.5% by mass or less and at the same time, at aComponent (F)/Component (A) mass ratio falling within a range of from 0to 0.5. The content of 2-benzyloxyethanol is preferably 0.5% by mass orless, more preferably 0.2% by mass or less from the standpoint ofpromoting manageability while imparting softness, luster feel and smoothfinger combability to the hair.

In the hair cosmetic composition of the present invention, aconditioning component selected from silicones and oily substances maybe incorporated in order to improve a conditioning effect further.Examples of the silicones include dimethylpolysiloxanes,polyether-modified silicones, amino-modified silicones, carboxy-modifiedsilicones, methylphenylpolysiloxane, fatty acid-modified silicones,alcohol-modified silicones, aliphatic alcohol-modified silicones,epoxy-modified silicones, fluorine-modified silicones, cyclic silicones,and alkyl-modified silicones. Of these, dimethylpolysiloxanes,polyether-modified silicones and amino-modified silicones are preferred.Dimethylpolysiloxanes can provide the hair with good lubricity,polyether-modified silicones can provide the hair with smoothness, andamino-modified silicones can provide the hair with moist feel. In thepresent invention, various silicones may be used either singly or incombination of two or more, depending on the desired performance. As thedimethylpolysiloxane, those having a viscosity of from about 5 mm²/s toabout 10 million mm²/s may be used depending on the desired feel of thehair, wherein those having a viscosity of about 10 million mm²/s areoften supplied in the form of an emulsion. Of these, those having aviscosity of from 5000 mm²/s to 10 million mm²/s are preferred, withthose having a viscosity of from 50000 mm²/s to 10 million mm²/s beingmore preferred. The term “polyether-modified silicones” is a genericname of polyoxyethylene/methylpolysiloxane copolymers andpoly(oxyethylene/oxypropylene)methylpolysiloxane copolymers and thosehaving various HLBs are known. Examples of the commercially availableproducts thereof include “Silicone KF351A”, “Silicone KF353A”, “SiliconeKF6008”, “Silicone KF6016”, “Silicone KF6011”, and “Silicone KF6012”,each, product of Shin-etsu Chemical, and “SH3771C”, “SH3773C”, and“SH3775C”, each, product of Dow Corning Toray. As the amino-modifiedsilicones, amodimethicone oil or an emulsion thereof is preferred. Theircommercially available products are, for example, amodimethiconeemulsion “SM8704C”, product of Dow Corning Toray, and“KT-1989”,“XF-42-B1989”, product of Momentive Performance MaterialsJapan.

The content of the silicones in the hair cosmetic composition of thepresent invention is preferably from 0.05 to 20% by mass, morepreferably from 0.1 to 10% by mass, even more preferably from 0.3 to 5%by mass in consideration of smooth finger combability andstickiness-free feel.

The oily substances are preferably used to improve the hairmanageability after drying. Examples thereof include hydrocarbons suchas squalene, squalane, liquid isoparaffin, light liquid isoparaffin,heavy liquid isoparaffin, α-olefin oligomer, liquid paraffin, andcycloparaffin; glycerides such as castor oil, cacao oil, mink oil,avocado oil, and olive oil; waxes such as sperm wax, lanolin,microcrystalline wax, ceresin wax, and carnauba wax; higher alcoholssuch as cetyl alcohol, oleyl alcohol, stearyl alcohol, isostearylalcohol, 2-octyldodecanol, myristyl alcohol, behenyl alcohol, andcetostearyl alcohol; esters such as octyldodecyl myristate, hexyllaurate, cetyl lactate, propylene glycol monostearate, oleyl oleate,hexadecyl 2-ethylhexanoate, isononyl isononanoate, and tridecylisononanoate; higher fatty acids such as capric acid, lauric acid,myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid,coconut oil fatty acid, isostearic acid, isopalmitic acid, and lanolinfatty acid; and other oily substances such as isostearyl glyceryl etherand polyoxypropylene butyl ether. Of these, branched hydrocarbonsincluding squalene, squalane, liquid isoparaffin, light liquidisoparaffin, heavy liquid isoparaffin, and α-olefin oligomer arepreferred.

The content of the oily substance in the hair cosmetic composition ofthe present invention is preferably from 0.05 to 20% by mass, morepreferably from 0.1 to 10% by mass, even more preferably from 0.5 to 5%by mass from the standpoint of good manageability and stickiness-freefeel.

The hair cosmetic composition of the present invention may furthercontain, according to the purpose of use, another component ordinarilyemployed for hair cosmetic compositions. Examples include organicsolvents other than Components (A) and (B) such as phenoxyethanol,propylene glycol, N-methylpyrrolidone, and propylene carbonate; polymercompounds such as cationic cellulose, hydroxyalkylated celluloses andhighly polymerized polyethylene oxide; anti-dandruffs such as zincpyrithione and benzalkonium chloride; vitamin preparations;bactericides; anti-inflammatory agents; preservatives; chelating agents;humectants such as panthenol; colorants such as dyes and pigments;extracts such as extract of Eucalyptus in a polar solvent, proteinavailable from a shell having a pearl layer or a pearl itself orhydrolysate of the protein, protein available from silk or hydrolysateof the protein, protein-containing extract available from seeds oflegume plants, Panax ginseng extract, rice bran extract, fucoid extract,camellia extract, aloe extract, Alpinia leaf extract, and chlorellaextract; pearl powder such as mica titanium; perfumes; coloring matters;ultraviolet absorbers; antioxidants; pH adjusters such as organic acidsother than Components (C) and (D), e.g., citric acid and glycolic acidand alkali agents, e.g., sodium hydroxide and potassium hydroxide; andcomponents listed in ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLEPRESS).

The hair cosmetic composition of the present invention preferably has apH (at 25° C.) of from 3.0 to 5.0 when diluted to 20 times the mass withwater. The hair cosmetic composition having a pH within theabove-described range has a function of repairing a hair damage causedby coloring or the like and is excellent in the function of giving goodsoftness and a supple touch to the hair during the period from wettingto after drying. The pH is adjusted to preferably from 3.2 to 4.7, morepreferably from 3.4 to 4.4 from the standpoint of the repairing effectof damaged hair. For pH adjustment, an acid substance such as inorganicacid or organic acid and a basic substance such as sodium hydroxide maybe used in combination. Examples of the organic acid include thoseexemplified above as Components (C) and (D).

The form of the hair cosmetic composition of the present invention maybe selected from liquid, gel, paste, cream, and wax as needed. Thecomposition in solution form using, as a solvent, water or a loweralcohol is preferred, with the composition in aqueous solution formbeing more preferred.

The hair cosmetic composition of the present invention is usedpreferably as a hair conditioning agent or hair styling agent. It may beprovided, for example, as a pump spray, aerosol spray, pump foam,aerosol foam, gel, or lotion.

The hair cosmetic composition of the present invention can provide ahair-quality improving effect when applied to the hair and left on thehair without rinsing it away. The term “left on the hair without rinsingit away” means that the hair cosmetic composition is left on the hairfor at least 3 hours, preferably at least 6 hours from its applicationto the hair to shampooing thereafter.

Treatment of the hair with the hair cosmetic composition of the presentinvention, at least once in two days and at least two times, preferablythree times in total is effective for improving the manageability of thehair itself and finger combability.

EXAMPLES Examples 1 to 11, Comparative Examples 1 to 20

The hair cosmetic compositions shown in Tables 2 to 4 are prepared in aconventional manner and evaluated using the following method inaccordance with the following criteria.

Evaluation methods of “spreadability and affinity upon application towet hair”, “finger combability upon application to wet hair”,“spreadability and affinity upon application to dry hair”, “fingercombability upon application to dry hair”, “finger combability of dryhair after successive three times application”, and “improvement inmanageability of hair after successive three times application”.

1) Hair Tress to be Evaluated (Common to Every Evaluation)

A hair tress of 15 cm in length, 3 cm in width and 3 g in weight isprepared by using the hair of a Japanese female not subjected tochemical treatment such as permanent waving and hair coloring. The hairtress is bleached (with “Prettia”, soft bubble bleach Hi-bleach; productof Kao Corporation) two times and the resulting hair tress is providedfor the evaluation.

2) Treatment of the Hair Tress 2-1) Hair Tresses for Evaluating“Spreadability and Affinity Upon Application to Wet Hair” and “FingerCombability Upon Application to Wet Hair”

The hair tresses to be evaluated were shampooed with a plain shampoo(“Curel”, a shampoo manufactured by Kao Corporation, which willhereinafter be called “plain shampoo”) and towel-dried. Then, 0.3 g ofeach of the hair cosmetic compositions shown in Tables 2 to 4 wasapplied uniformly to each of the resulting hair tresses andspreadability and affinity of the composition were evaluated. The fingercombability of each hair tress was then evaluated by using the hairtress combed with a ring comb (“New Delrin metaling Comb No. 1”, productof Delrin, which will hereinafter be called “ring comb”) for 10 seconds.

2-2) Hair Tresses for Evaluating “Spreadability and Affinity UponApplication to Dry Hair” and “Finger Combability Upon Application to DryHair”

The hair tresses to be evaluated were shampooed with the plain shampooand towel-dried. The resulting hair tresses were each dried by combingit with the ring comb for 5 minutes under warm wind of 70° C. Then, 0.3g of each of the hair cosmetic compositions shown in Tables 2 to 4 wasapplied to the resulting hair tress uniformly and spreadability andaffinity of the composition were evaluated. Then, the hair tress combedwith the ring comb for 10 seconds was evaluated for its fingercombability.

2-3) Hair Tresses for Evaluating “Finger Combability of Dry Hair AfterSuccessive Three Times Application” and “Improvement in Manageability ofHair After Successive Three Times Application”

The hair tresses to be evaluated were shampooed with the plain shampooand towel-dried. Then, 0.3 g of each of the hair cosmetic compositionsshown in Tables 2 to 4 was applied to each of the resulting hair tressesand dried by combing it with the ring comb for 5 minutes under warm windof 70° C. The warm wind used here has, as well as a function of dryingthe hair tress, a function of promoting the state under which thecomposition is left to stand in evaluating the effect produced byleaving the composition without rinsing it away. The treatment fromshampooing to drying was performed three times in total.

With regard to the “finger combability of dry hair after successivethree times application”, finger combability after the treatment (beforeshampooing) and that after the treatment, shampooing and then drying ina similar manner (after shampooing) were evaluated.

With regard to the “improvement in manageability of hair aftersuccessive three times application”, the improvement after the treatment(before shampooing) and that after the treatment, shampooing and dryingin a similar manner (after shampooing) were evaluated after leaving thehair tress for 15 minutes under normal environment (60% RH, 25° C.) andhigh-humidity environment (90% RH, 25° C.).

3) Evaluation Criteria

Sensual evaluation was made by a panel of five experts in accordancewith the table of evaluation criteria shown in Table 1. Each expertevaluated with from 1 to 5 scores. In Tables 2 to 4, a total evaluationscore of five experts is shown.

TABLE 1 5 4 3 2 1 Spreadability and affinity upon Superior A little MeanA little Inferior application to wet hair superior Inferior Fingercombability upon application to Superior A little Mean A little Inferiorwet hair superior Inferior Spreadability and affinity upon Superior Alittle Mean A little Inferior application to dry hair superior InferiorFinger combability upon application to Superior A little Mean A littleInferior dry hair superior Inferior Finger combability of dry hair afterSuperior A little Mean A little Inferior successive three timesapplication superior Inferior Improvement in manageability of hairSuperior A little No A little Inferior after successive three timesapplication superior improvement Inferior (comparison with that beforetreatment)

TABLE 2 Examples (% by mass) 1 2 3 4 5 6 7 8 9 10 11 (A) Benzyl alcohol0.2 0.5 0.3 1 0.2 2 0.18 1.5 0.4 0.4 0.2 (B) Dipropylene glycol 2 3 5 52 1 10 2 15 17.6 2 (C) Malic acid 0.6 0.3 0.3 0.3 8 0.6 0.6 0.6 0.3 0.35 (D) Lactic acid 0.6 0.3 0.3 0.3 8 0.6 0.6 0.6 0.3 0.3 5 (E)Polyoxyethylene hydrogenated 0.6 1.5 1 1.5 0.6 0.6 0.6 0.6 1 1 0.6castor oil (40EO) (F) 2-Benzyloxyethanol — — — — — — — 0.6 — — — pHAdjuster (sodium q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s.hydroxide/citric acid) Purified water Bal- Bal- Bal- Bal- Bal- Bal- Bal-Bal- Bal- Bal- Bal- ance ance ance ance ance ance ance ance ance anceance (E)/(A) Mass ratio 3 3 3.3 1.5 3 2 3.3 0.4 2.5 2.5 3 (C) + (D) 1.20.6 0.6 0.6 16 1.2 1.2 1.2 0.6 0.6 10 (B)/(A) Mass ratio 10 6 16.7 5 100.5 55.6 1.3 37.5 44 10 pH (When diluted to 20 times with water, 25° C.)3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 Evalu- Before Spreadabilityand 25 24 22 21 22 19 21 19 24 19 23 ation shampooing affinity uponappli- cation to wet hair Finger combability 23 22 22 21 16 18 19 17 2118 21 upon application to wet hair Spreadability and 25 24 22 21 22 1819 18 22 17 23 affinity upon appli- cation to dry hair Fingercombability 23 22 23 22 18 17 18 14 22 16 21 upon application to dryhair Finger combability 24 23 24 23 19 17 19 16 23 20 22 of dry hairafter successive three times application Improvement in 23 25 25 25 2422 21 22 24 25 25 manageability of hair after successive three timesapplication Manageability of 22 24 25 25 23 21 20 21 21 23 24 hair underhigh humidity after successive three times application After Fingercombability 22 22 22 21 17 16 16 16 20 17 22 shampooing of dry hairafter successive three times application Improvement in 22 23 23 24 2221 20 23 22 22 23 manageability of hair after successive three timesapplication Manageability of 21 23 22 23 21 20 19 22 20 20 21 hair underhigh humidity after successive three times application

TABLE 3 Comparative Examples (% by mass) 1 2 3 4 5 6 7 8 9 10 11 12 1314 (A) Benzyl alcohol — 0.05 5 0.2 0.2 0.2 0.5 0.5 0.5 0.5 0.5 0.5 0.60.15 (B) Dipropylene glycol 2 2 2 — 0.05 25 2 2 2 2 2 2 2 2 (C) Malicacid 0.6 0.6 0.6 0.6 0.6 0.6 — 0.05 15 0.6 0.6 0.6 0.6 0.6 (D) Lacticacid 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 — 0.05 15 0.6 0.6 (E)Polyoxyethylene hydrogenated 0.6 0.2 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.60.6 2.5 1 castor oil (40EO) pH Adjuster(Na q.s. q.s. q.s. q.s. q.s. q.s.q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. hydroxide/citric acid) Purifiedwater Bal- Bal- Bal- Bal- Bal- Bal- Bal- Bal- Bal- Bal- Bal- Bal- Bal-Bal- ance ance ance ance ance ance ance ance ance ance ance ance anceance (E)/(A) Mass ratio — 4 0.12 3 3 3 1.2 1.2 1.2 1.2 1.2 1.2 4.2 6.7(C) + (D) 1.2 1.2 1.2 1.2 1.2 1.2 0.6 0.65 15.6 0.6 0.65 15.6 1.2 1.2(B)/(A) Mass ratio — 40 0.4 — 0.25 125 4 4 4 4 4 4 3.3 13.3 pH (Whendiluted to 20 times with water, 25° C.) 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.73.7 3.7 3.7 3.7 3.7 3.7 Evalu- Before Spreadability and 14 16 14 14 13 914 14 12 12 15 11 12 13 ation shampooing affinity upon appli- cation towet hair Finger combability 14 14 9 13 13 8 13 13 6 11 13 7 9 11 uponapplication to wet hair Spreadability and 14 15 13 13 14 9 16 14 9 11 1411 11 14 affinity upon appli- cation to dry hair Finger combability 1313 7 12 12 7 14 13 7 7 11 6 9 11 upon application to dry hair Fingercombability 16 16 7 12 13 8 14 14 7 6 11 7 10 10 of dry hair aftersuccessive three times application Improvement in 15 16 14 14 13 11 1414 15 17 14 16 19 13 manageability of hair after successive three timesapplication Manageability of 14 16 12 12 13 11 14 13 14 15 12 15 20 11hair under high humidity after successive three times application AfterFinger combability 11 11 13 9 9 12 8 12 7 9 8 8 14 13 shampooing of dryhair after successive three times application Improvement in 13 14 21 1315 23 10 11 21 14 18 22 18 12 manageability of hair after successivethree times application Manageability of 12 14 20 13 14 23 10 11 20 1219 23 17 11 hair under high humidity after successive three timesapplication

TABLE 4 Comparative Examples (% by mass) 15 16 17 18 19 20 (A) Benzylalcohol 0.2 — 2.5 0.2 — 0.2 (B) Dipropylene glycol 3 — — 3 2 — (C) Malicacid 0.1 2.5 2.5 0.1 0.6 0.6 (D) Lactic acid 0.5 2.5 2.5 0.5 0.6 0.6 (E)Polyoxyethylene hydrogenated — 0.25 0.25 — 0.6 0.6 castor oil (40EO)Stearic acid dimethylaminopropylamide 2 — — — — — Octylamidopropylbenzalkonium chloride 0.3 — — — — — Stearyl trimethylammonium chloride —0.25 0.25 — — — Behenic acid dimethylaminopropylamide (*) — — — 2 — —Behenyltrimethylammonium chloride — — — 0.3 — — (F) 2-Benzyloxyethanol —2.5 — — 0.2 — Propylene glycol — — 2.5 — — 2.0 pH Adjuster (sodium q.s.q.s. q.s. q.s. q.s. q.s. hydroxide/citric acid) Purified water Bal- Bal-Bal- Bal- Bal- Bal- ance ance ance ance ance ance (E)/(A) Mass ratio11.5 — 0.2 11.5 — 3 (C) + (D) 0.6 5 5 0.6 1.2 1.2 (B)/(A) Mass ratio 15— — 15 — — pH (when diluted to 20 times with water, 25° C.) 3.2 3.7 3.73.7 3.7 3.7 Evalu- Before Spreadability and affinity upon 14 19 14 15 1818 ation shampooing application to wet hair Finger combability uponapplication 13 18 12 14 18 16 to wet hair Spreadability and affinityupon 9 19 12 11 14 14 application to dry hair Finger combability uponapplication 9 12 11 8 13 14 to dry hair Finger combability of dry hairafter 12 12 12 9 13 14 successive three times application Improvement inmanageability of hair 12 16 13 15 14 14 after successive three timesapplication Manageability of hair under high humidity 13 15 12 13 13 14after successive three times application After Finger combability of dryhair after 11 14 10 14 18 13 shampooing successive three timesapplication Improvement in manageability of hair after 11 11 17 16 16 13successive three times application Manageability of hair under highhumidity 11 9 16 16 16 12 after successive three times application (*):obtained by the reaction between behenic acid anddimethylaminopropylamine (fatty acid composition: C₁₈C₂₀/C₂₂/C₂₄ =1/9/88/2)

Example 12 Pump Spray

(% by mass) Benzyl alcohol 0.3 2-Benzyloxyethanol 0.05 Dipropyleneglycol 3.0 Malic acid 0.4 Lactic acid 0.4 Glycerin 1.0 Ethanol 5.0Perfume 0.03 Sodium hydroxide adjusted to pH 3.7 (when diluted to 20times its mass with water) Water Balance

Example 13 Pump Mist

(% by mass) Benzyl alcohol 0.5 Dipropylene glycol 4.0 Malic acid 0.6Lactic acid 0.6 Polyvinylpyrrolidone 3.0 Ethanol 10.0 Perfume 0.02Sodium hydroxide adjusted to pH 3.7 (when diluted to 20 times its masswith water) Water Balance

Example 14 Hair Gel

(% by mass) Benzyl alcohol 1.0 Dipropylene glycol 5.0 Glycerin 2.0Stearyl trimethylammonium chloride 0.25 Malic acid 0.3 Lactic acid 0.3Hydroxyethyl cellulose 2.0 Ethanol 5.0 Perfume 0.05 Sodium hydroxideadjusted to pH 3.7 (when diluted to 20 times its mass with water) WaterBalance

Example 15 Aerosol Spray

<Stock Solution> (% by mass) Benzyl alcohol 0.3 Dipropylene glycol 3.0Malic acid 0.5 Lactic acid 0.5 Stearyl trimethylammonium chloride 0.25Glycerin 1.0 Perfume 0.02 Sodium hydroxide adjusted to pH 3.7 (whendiluted to 20 times its mass with water) Water Balance

<Propellant>

-   Nitrogen gas

<Stock Solution/Propellant Mass Ratio> 99.5/0.5 Example 16 Pump Foam

(% by mass) Benzyl alcohol 0.4 Dipropylene glycol 2.5 Malic acid 0.7Lactic acid 0.7 Polyoxyethylene (16) lauryl ether 1.0Stearyltrimethylammonium chloride 0.25 Glycerin 1.0 Ethanol 5.0 Perfume0.03 Sodium hydroxide adjusted to pH 3.7 (when diluted to 20 times itsmass with water) Water Balance

Example 17 Aerosol Foam

<Stock Solution> (% by mass) Benzyl alcohol 1.0 Dipropylene glycol 7.0Malic acid 1.0 Lactic acid 0.2 Polyoxyethylene (16) lauryl ether 1.0Cetyl trimethylammonium chloride 0.25 Glycerin 1.0 Ethanol 4.5 Perfume0.03 Sodium hydroxide adjusted to pH 3.7 (when diluted to 20 times itsmass with water) Water Balance

<Propellant>

-   LPG (0.44 MPa)

<Stock Solution/Propellant Mass Ratio> 93.0/7.0 Example 18 Hair Lotion

(% by mass) Benzyl alcohol 0.5 Dipropylene glycol 2.5 Malic acid 2.5Lactic acid 2.5 Stearyl trimethylammonium chloride 0.12 Cetyltrimethylammonium chloride 0.12 Polyethylene glycol 400 0.45 Ethanol 4.5Perfume 0.03 Sodium hydroxide adjusted to pH 3.7 (when diluted to 20times its mass with water) Water Balance

1. A hair cosmetic composition, comprising the following Components (A) to (E): (A) benzyl alcohol, from 0.1 to 2% by mass; (B) dipropylene glycol, from 0.5 to 20% by mass; (C) malic acid or a salt thereof, from 0.2 to 10% by mass, in terms of the malic acid; (D) lactic acid or a salt thereof, from 0.2 to 10% by mass, in terms of the lactic acid; and (E) a nonionic surfactant, with the proviso that polyoxyethylene hydrogenated castor oil is excluded, 2% by mass or less, wherein a Component (E)/Component (A) mass ratio is from 0 to 5, and wherein a Component (B)/Component (A) mass ratio is from 1 to
 50. 2. The hair cosmetic composition according to claim 1, wherein the Component (E) is selected from the group consisting of a polyoxyalkylene alkyl ether, a polyoxyalkylene alkenyl ether, a higher fatty acid sucrose ester, a polyglycerin fatty acid ester, a higher fatty acid monoethanolamide, a higher fatty acid diethanolamide, a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene sorbitol fatty acid ester, an alkyl saccharide surfactant, an alkylamine oxide, and an alkyl amidoamine oxide.
 3. The hair cosmetic composition according to claim 1, wherein the Component (E) is a polyoxyalkylene alkyl ether.
 4. The hair cosmetic composition according to claim 1, wherein the Component (E) in at an amount of 0.02 to 2% by mass.
 5. The hair cosmetic composition according to claim 1, wherein the Component (E) in at an amount of 0.05 to 1.5% by mass.
 6. The hair cosmetic composition according to claim 1, wherein a total content of Components (C) and (D) is from 0.4 to 15% by mass.
 7. The hair cosmetic composition according to claim 1, wherein a Component (B)/Component (A) mass ratio is from 3 to
 45. 8. The hair cosmetic composition according to claim 1, further comprising 2-benzyloxyethanol as Component (F) at a concentration of 0.5% by mass or less and at a Component (F)/Component (A) mass ratio falling within a range of 0 to 0.5, wherein Component (F) is present in a non-zero amount.
 9. The hair cosmetic composition according to claim 1, having a pH at 25° C. of from 3.0 to 5.0 when diluted to 20 times the mass with water.
 10. A hair-quality improving method, comprising applying the hair cosmetic composition according to claim 1 to hair and leaving the hair without rinsing.
 11. The hair-quality improving method according to claim 10, wherein the hair cosmetic composition is applied to the hair at least once in two days and, in total, at least two times.
 12. The hair-quality improving method according to claim 10, wherein said leaving the hair without rinsing comprises leaving said cosmetic composition on the hair for at least hours following said applying to the hair followed by rinsing said hair.
 13. The hair-quality improving method according to claim 12, wherein said rinsing comprises shampooing.
 14. The hair-quality improving method according to claim 10, wherein said leaving the hair without rinsing comprises leaving said cosmetic composition on the hair for at least 6 hours following said applying to the hair followed by rinsing said hair.
 15. The hair-quality improving method according to claim 14, wherein said rinsing comprises shampooing. 